DIRECT ASYMMETRIC alpha-ALLYLATION OF KETONES WITH ALLYLIC ALCOHOLS VIA Pd/ENAMINE COOPERATIVE FUNCTION

[摘要]：Direct asymmetric alpha-allylation of ketones with allylic alcohols is described. The combination of palladium with a new phosphine ligand bearing a chiral proline moiety promoted the reaction to afford the corresponding alpha-allylated ketones in moderate yield and enantioselectivity.

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