【文章名】Reactions of unsaturated azides; Part 22: The alkyne azide click chemistry as a synthetic tool for the generation of cage-like triazole compounds.
[摘要]:The applicability of the Cu(I)-catalyzed click reaction of terminal trialkynes with triazides to the synthesis of cage-like triazole compds. was detd. A no. of starting materials were prepd. and several monotriazoles as well as macrocyclic bistriazoles were obtained from the triazide trialkyne reaction. Finally, a tristriazole macrobicyclic compd. was synthesized from the previously formed triazole precursors.