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Synthesis and Properties of a Novel Photochromic Compound with Modulated Fluorescence in the Solid State

  作者 LIU LANG; XIE XIANGYUN; JIA DIANZENG; GUO JIXI; XIE XIAOLIN  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-14;  页码  4742-4747  
  关联知识点  
 

[摘要]A new photochromic compound, 1,3-diphenyl-4-(3-bromobenzal)-5-hydroxypyrazole 4-phenylsemicarbazone (DP3BrBP-PSC), has been prepared. Its photochromic and thermobleaching behavior, crystal structure, and fluorescent property have been investigated in detail. The results show that the compound exhibits reversible enol keto photoisomerization due to the intermolecular double-proton transfer, excellent photostability, high fatigue resistance, and remarkable fluorescence.

 
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