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Coordination of aminoborane, NH2BH2, dictates selectivity and extent of H2 release in metal-catalysed ammonia borane dehydrogenation.

  作者 Pons, Vincent;Baker, R. Tom;Szymczak, Nathaniel K.;Heldebrant, David J.;Linehan, John C.;Matus, Myrna H.;Grant, Daniel J.;Dixon, David A.;  
  选自 期刊  Chemical Communications;  卷期  2008年-48;  页码  6597-6599  
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[摘要]In situ 11B NMR monitoring, computational modeling, and external trapping studies show that selectivity and extent of H2 release in metal-catalyzed dehydrogenation of ammonia borane, NH3BH3, are detd. by coordination of reactive aminoborane, NH2BH2, to the metal center.

 
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