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2-Pyrazolin-5-ones bearing a basic dialkylaminoalkyl substituent at the N1-position: preparation and NMR spectroscopic investigations.

  作者 Wolf, Barbara M. T.;Eller, Gernot A.;Holzer, Wolfgang;  
  选自 期刊  Heterocycles;  卷期  2008年75-8, 7/30/08;  页码  2035-2042  
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[摘要](Heterocyclic Compounds (More Than One Hetero Atom)) Section 2-Pyrazolin-5-ones (tautomers to 5-hydroxypyrazols) bearing dialkylaminoyalkyl substituents at the ring nitrogen atom N-1 are prepd. from the corresponding hydrazines and beta-ketoesters. Detailed NMR spectroscopic investigations (1H, 13C, 15N) with the obtained compds. are undertaken and the tautomerism of such pyrazolones in soln. is discussed.

 
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