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The maize benzoxazinone DIMBOA reacts with glutathione and other thiols to form spirocyclic adducts

  作者 Dixon, DP; Sellars, JD; Kenwright, AM; Steel, PG  
  选自 期刊  Phytochemistry;  卷期  2012年77-1;  页码  171-178  
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[摘要]Maize, wheat and other grasses synthesise large quantities of benzoxazinones and their glucosides, which act as antifeedant and allelopathic agents. These activities are probably due to the electrophilic nature of the aglycones, however, the mechanism of

 
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