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Selectivity in Metal-Catalyzed Carbon-Carbon Bond Cleavage of Alkylidenecyclopropanes

  作者 MASARWA AHMAD; MAREK ILAN  
  选自 期刊  Chemistry-A European Journal;  卷期  2010年16-32;  页码  9712-9721  
  关联知识点  
 

[摘要]When more complex system leads to simpler reactivity profile the ring-opening of strained three-membered rings such as methylene- and alkylidenecyclopropanes generally lead to several products If one starts with more functionalized carbon skeletons, selective reactions are now observed and rationalization as well as synthetic applications are described in this concept article. This methodology could be used to the preparation of challenging structural motifs possessing quaternary carbon stereocenters in acyclic systems

 
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