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Enantioselective 1,6-Conjugate Addition to Cyclic Dienones Catalyzed by the Cu-DiPPAM Complex

  作者 WENCELDELORD JOANNA; ALEXAKIS ALEXANDRE; CREVISY CHRISTOPHE; MAUDUIT MARC  
  选自 期刊  Organic Letters;  卷期  2010年12-19;  页码  4335-4337  
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[摘要]In the presence of a Cu/DiPPAM catalytic system, various diorganozinc reagents realize 1,6-asymmetric conjugate addition on various cyclic five- and six-membered cyclic dienones, with complete regioselectivity and high ee's (93-99%).

 
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