Enantioselective 1,6-Conjugate Addition to Cyclic Dienones Catalyzed by the Cu-DiPPAM Complex
[摘要]:In the presence of a Cu/DiPPAM catalytic system, various diorganozinc reagents realize 1,6-asymmetric conjugate addition on various cyclic five- and six-membered cyclic dienones, with complete regioselectivity and high ee's (93-99%).
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