Total Syntheses of (+)-Pestaphthalide A and (-)-Pestaphthalide B

[摘要]：Total syntheses of (+)-pestaphthalide A and (-)-pestaphthalide B were achieved. Key steps are an iridium-mediated meta-selective arylborylation, a Suzuki-coupling/Jacobsen-epoxidation sequence, a stereodivergent epoxide opening and an anionic cyclic carbonate/gamma-lactone rearrangement.

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