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Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)(2)

  作者 JANJETOVIC MARIO; TRAFF ANNIKA M; ANKNER TOBIAS; WETTERGREN JENNY; HILMERSSON GORAN  
  选自 期刊  Chemical Communications;  卷期  2013年49-18;  页码  1826-1828  
  关联知识点  
 

[摘要]Sm(HMDS)(2) in n-hexane mediates fast cleavage of primary, secondary and tertiary alkyl fluorides in good to excellent yields. In n-hexane Sm(HMDS)(2) exhibits uniquely enhanced reductive ability towards the C-F bond compared to when using THF as solvent.

 
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