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Chemoselective (Trans)thioacetalization of Carbonyl Compounds with a Reusable Lewis Acid-Surfactant-Combined Copper Bis(dodecyl sulfate) Catalyst in Water

  作者 WENG SHIUESHIEN; CHANG SHENCHUN; CHANG TSUANHAO; CHYN JONGPYNG; LEE SHUWEI; LIN CHAOAN; CHEN FONGKUANG  
  选自 期刊  Synthesis;  卷期  2010年-9;  页码  1493-1499  
  关联知识点  
 

[摘要]A Lewis acid-surfactant-combined copper bis(dodecyl sulfate) [Cu(DS)(2)] catalyst served as an efficient and reusable catalyst for the thioacetalization and transthioacetalization of carbonyl compounds and O,O-acetals in water at room temperature. Some of the major advantages of this procedure are high chemoselectivity, ease of operation and purification without any organic solvent, and high yields.

 
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