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Stereoselective synthesis of 2-[1-methylpyridin-2(1H)-ylidene]malononitrile derivatives.

  作者 Khoroshilov, Gennadiy;Demchak, Ivan;Saraeva, Tatjana;  
  选自 期刊  Synthesis;  卷期  2008年-10;  页码  1541-1544  
  关联知识点  
 

[摘要]An efficient synthesis of 2-[1-methylpyridin-2(1H)-ylidene]malononitrile derivs. is described by coupling of 2-chloro-N-methylpyridinium chloride with appropriate nitriles. The reactions proved to be stereoselective. The spatial location of substituents was detd.

 
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