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Towards the Total Synthesis of 3-Hydroxyvibsanin E

  作者 SCHWARTZ BRETT D; DENTON JUSTIN R; BERNHARDT PAUL V; DAVIES HUW M L; WILLIAMS CRAIG M  
  选自 期刊  Synthesis;  卷期  2009年-17;  页码  2840-2846  
  关联知识点  
 

[摘要]The synthesis of a silyl-protected derivative of 3-hydroxyvibsanin E has been achieved. The key step is a regio- and stereoselective C-H hydroxylation of an advanced tricyclic intermediate by means of a Rubottom oxidation.

 
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