【文章名】New Rearrangement of Conjugated Cyclic Ene Nitroso O-Trimethylsilyl Acetals: Convenient Synthesis of Dihydro-2H-pyran-3-one and Dihydrofuran-3-one Oximes
New Rearrangement of Conjugated Cyclic Ene Nitroso O-Trimethylsilyl Acetals: Convenient Synthesis of Dihydro-2H-pyran-3-one and Dihydrofuran-3-one Oximes
作者
TABOLIN ANDREY A; KHOMUTOVA YULIA A; NELYUBINA YULIA V; IOFFE SEMA L; TARTAKOVSKY VLADIMIR A
[摘要]：The nucleophile-induced rearrangement of cyclic N-alkoxy-N-(silyloxy)enamines was investigated. As a result, a new strategy for the synthesis of beta-pyranone and beta-furanone derivatives from nitro compounds is suggested.
