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TBAF-Promoted Elimination of Vicinal Dibromides Having an Adjacent O-Functional Group: Syntheses of 2-Bromoalk-1-enes and Alkynes

  作者 KUTSUMURA NORIKI; KUBOKAWA KEISUKE; SAITO TAKAO  
  选自 期刊  Synthesis;  卷期  2011年-15;  页码  2377-2382  
  关联知识点  
 

[摘要]Syntheses of 2-bromoalk-1-enes and alkynes were achieved in good yields by dehydrobromination of vicinal dibromides with tetrabutylammonium fluoride. Neighboring O-functional-group participation is important in determining elimination reactivity.

 
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