Synthetic Study of Versipelostatin A: Synthesis of the Spirotetronate Unit Starting from Pulegone

[摘要]：The synthesis of the spirotetronate unit of versipelostatin A, a down-regulator of molecular chaperone GRP78, was achieved in ten steps starting from pulegone, via the Johnson-Claisen rearrangement. A model study of the coupling reaction with the octalin unit was also performed.

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