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Isotopic Evidence for Massive Oxidation of Organic Matter Following the Great Oxidation Event

  作者 Kump, LR; Junium, C; Arthur, MA; Brasier, A; Fallick, A; Melezhik, V; Lepland, A; Crne, AE; Luo, GM  
  选自 期刊  Science;  卷期  2011年334-6063;  页码  1694-1696  
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[摘要]The stable isotope record of marine carbon indicates that the Proterozoic Eon began and ended with extreme fluctuations in the carbon cycle. In both the Paleoproterozoic [2500 to 1600 million years ago (Ma)] and Neoproterozoic (1000 to 542 Ma), extended intervals of anomalously high carbon isotope ratios (delta C-13) indicate high rates of organic matter burial and release of oxygen to the atmosphere; in the Neoproterozoic, the high delta C-13 interval was punctuated by abrupt swings to low delta C-13, indicating massive oxidation of organic matter. We report a Paleoproterozoic negative delta C-13 excursion that is similar in magnitude and apparent duration to the Neoproterozoic anomaly. This Shunga-Francevillian anomaly may reflect intense oxidative weathering of rocks as the result of the initial establishment of an oxygen-rich atmosphere.

 
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