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Oxidative C-C Bond Cleavage of Aldehydes via Visible-Light Photoredox Catalysis

  作者 SUN HONGNAN; YANG CHAO; GAO FEI; LI ZHE; XIA WUJIONG  
  选自 期刊  Organic Letters;  卷期  2013年15-3;  页码  624-627  
  关联知识点  
 

[摘要]The visible-light mediated oxidative C-C bond cleavage of aldehydes has been achieved in good yields at ambient temperature and open to air using Ru(bpy)(3)Cl-2 (bpy = 2,2'-bipyridine) as the photoredox catalyst Moreover, we further demonstrated the application in a tandem Michael/oxidative C C bond cleavage reaction.

 
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