STEREOSELECTIVE SYNTHESIS OF 2,3,5-TRISUBSTITUTED PYRROLIDINES USING METATHESIS-DERIVED beta-AMINOALLYLSILANES
[摘要]:Amine-functionalised allylsilanes, readily prepared by olefin cross metathesis of protected homoallylamines with allyltrimethylsilane, undergo stereoselective condensation with aldehydes to yield trisubstituted pyrrolidines.
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