MEMORY OF CHIRALITY IN THE ELECTROCHEMICAL OXIDATION OF N-o-PHENYLBENZOYLATED PROLINOLS

[摘要]：Memory of chirality in electrochemical carbon-carbon bond cleavage of N-o-phenylbenzoylated (S)-prolinol derivatives was observed. Substituents of the alpha-position affected the ee of the products. The reaction of alpha,alpha-diarylated (S)-prolinol derivatives proceeded smoothly to afford optically active alpha-methoxylated pyrrolidine with up to 73% ee.

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