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Tsuji-Trost N-Allylation with Allylic Acetates by Using a Cellulose-Palladium Catalyst

  作者 VADDULA BUCHI REDDY; SAHA AMIT; VARMA RAJENDER S; LEAZER JOHN  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2012年-34;  页码  6707-6709  
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[摘要]Allylic amines were synthesized by a simple procedure using a biodegradable and easily recyclable heterogeneous cellulosePd catalyst through N-allylation of primary and secondary amines. The scope of this protocol includes aliphatic and benzylamines with substituted and unsubstituted allyl acetates and culminates in high yield syntheses. The highlights of the protocol include a ligand-free reaction, simple workup, and catalyst recyclability.

 
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