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gamma-Radiation-induced dechlorination of 2,4-dichlorophenoxyacetate in an aqueous alcohol solution in the presence of oxygen

  作者 Kosobutskii, V. S.  
  选自 期刊  HIGH ENERGY CHEMISTRY;  卷期  2009年43-2;  页码  80-82  
  关联知识点  
 

[摘要]The buildup of chloride ions at sodium 2,4-dichlorophenoxyacetate concentrations of 0.0002-0.01 mol/l in oxygen-saturated 2 mol/l propanol-2 aqueous solutions was studied. The main contribution to the dehalogenation of 2,4-dichlorophenoxyacetate is made by hydrated electrons. The dissociation rate constant for the 2,4-dichlorophenoxyacetate radical anion was determined with the use of the scavenging technique.

 
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