SYNTHESIS AND MESOMORPHISM OF THE BIPEDAL LIQUID CRYSTALS WITH A TETRATHIAFULVALENE/DITHIOLE AND TWO CHOLESTEROL MOIETIES

[摘要]：The bipedal 1,3-dithiole-2-thiones and the appropriate EDT-TTFs bearing two cholesteryl linked with two omega-thioalkanoyloxy spacers of varying length were synthesized. All of bipedals showed mesogenic phases in a wide temperature region, no crystallization but vitrifying to form glassy mesogens during cooling from the isotropic melt.

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