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Phosphane-Catalyzed [4+2] Annulation of Allenoates with Ketimines: Synthesis of Sultam-Fused Tetrahydropyridines

  作者 CHEN XIANGYU; YE SONG  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2012年-29;  页码  5723-5728  
  关联知识点  
 

[摘要]Cyclic ketimines were successfully used as electrophiles in phosphane-catalyzed [4+2] annulation reactions with ethyl 2-methyl-2,3-butadienoate to give the corresponding highly substituted tetrahydropyridine derivatives in moderate to good yields (5573?%), and with moderate to excellent regioselectivity.

 
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