A Formal Total Synthesis of Fostriecin by a Convergent Approach

[摘要]：A formal total synthesis of fostriecin has been accomplished in 20 steps. Our method features the derivation of two of the four chiral centers from commercial diethyl D-(+)-malate. The key steps involve the Julia-Kocienski olefination, the Sharpless asymmetric dihydroxylation, and the Stille coupling.

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