Highly Enantioselective Synthesis of (Diarylmethyl)amines by Rhodium-Catalyzed Arylation of N-Nosylimines Using a Chiral Bicyclo[3.3.0]diene Ligand

[摘要]：A highly efficient asymmetric arylation of N-nosylimines with arylboronic acids catalyzed by a rhodium-diene complex is described. A wide range of enantiopure (98-99% ee) N(diarylmethyl)nosylamides, as well as (3S)-2-(4-nosyl)-3-phenyl-isoindolin-1-one, were obtained in high yields (83-99%) under very mild conditions.

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