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Total Synthesis of (+)-Cryptocaryalactone and of a Diastereoisomer of (+)-Strictifolione via Ring-Closing Metathesis (RCM) and Olefin Cross-Methathesis (CM)

  作者 Sabitha, G; Vangala, B; Reddy, SSS; Yadav, JS  
  选自 期刊  Helvetica Chimica Acta;  卷期  2010年93-2;  页码  329-338  
  关联知识点  
 

[摘要]Ring-closing metathesis (RCM) and olefin cross-metathesis (CM) reactions were used as the key steps for the synthesis of (+)-cryptocaryalactone (1) and the first synthesis of the diastereoisomer 3 of (+)-strictifolione, starting from the commercially available L-malic acid (=(2,5)-2-hydroxybutanedioic acid).

 
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