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A General Procedure for the Synthesis of Unsymmetrically Substituted Tris(beta-oximinoalkyl)amines

  作者 SEMAKIN ARTEM N; SUKHORUKOV ALEXEY YU; IOFFE SEMA L; TARTAKOVSKY VLADIMIR A  
  选自 期刊  Synthesis;  卷期  2011年-9;  页码  1403-1412  
  关联知识点  
 

[摘要]A first general approach to the synthesis of unsymmetrically substituted tris(beta-oximinoalkyl)amines containing two or three different beta-oximinoalkyl fragments has been developed. This procedure employs available aliphatic nitro compounds as starting building blocks and their silylation as the key step. This approach provides an efficient strategy for the diversity-oriented synthesis of 1,4,6,10-tetraazaadamantane derivatives.

 
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