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Synthesis of Benzannulated Spiroketals Using an Oxidative Radical Cyclization

  作者 SPERRY JONATHAN; LIU YENCHENG WILLIAM; WILSON ZOE E; HUBERT JONATHAN G; BRIMBLE MARGARET A  
  选自 期刊  Synthesis;  卷期  2011年-9;  页码  1383-1398  
  关联知识点  
 

[摘要]The synthesis of both mono and bisbenzannulated spiroketals using an oxidative radical cyclization approach is investigated. Although unsuccessful in uncovering a novel route toward bisbenzannulated spiroketals, the oxidative radical cyclization does facilitate a new approach to monobenzannulated spiroketals such as those found in berkelic acid and in the chaetoquadrins.

 
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