Peracetylated beta-Allyl C-Glycosides of D-Ribofuranose and 2-Deoxy-D-ribofuranose in the Chemical Literature: Until Now, Mirages in the Literature

[摘要]：The peracetylated beta-allyl C-glycosides of D-ribofuranose (8) and 2-deoxy-D-ribofuranose (13) were stereoselectively prepared via the isopropylidene derivatives 3 and 4. These reactions represent what are, to the best of our knowledge, the first preparation of these apparently simple derivatives whose structures were carefully proved by NMR and X-ray investigations. Publications which allegedly described the synthesis of 8 and 13 were critically examined.

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