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A New Method for the Synthesis of Iminoquinones via DMP-Mediated Oxidative Reaction

  作者 MA HENGCHANG; WU SHANG; SUN QIANGSHENG; LI HONGYAN; CHEN YANNAN; ZHAO WENQING; MA BIHUI; GUO QING; LEI ZIQIANG; YAN JUN  
  选自 期刊  Synthesis;  卷期  2010年-19;  页码  3295-3300  
  关联知识点  
 

[摘要]Iminoquinones were synthesized by oxidation of primary and secondary amines with hypervalent iodine reagent Dess-Martin periodinane in average to good yields, and possible mechanisms were postulated. This methodology is convenient to establish a library of diversified iminoquinone compounds and has great significance for their potential application in the field of pharmaceuticals.

 
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