Palladium-Catalyzed Thiocarbonylation of Iodoarenes with Thiols in Phosphonium Salt Ionic Liquids.

[摘要]：Trihexyl(tetradecyl)phosphonium hexafluorophosphate, a phosphonium salt ionic liq. (PSIL) is a particularly effective general reaction media for the Pd-catalyzed carbonylation reaction of iodoarenes and thiols to form thioesters. Recycling of the ionic liq. contg. active Pd-catalyst was also demonstrated.

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