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Water-Dependent Reduction of Carbohydrate Azides by Dithiothreitol

  作者 KOMAROVA BOZHENA S; MARYASINA SOFIA S; TSVETKOV YURY E; NIFANTIEV NIKOLAY E  
  选自 期刊  Synthesis;  卷期  2013年45-4;  页码  471-478  
  关联知识点  
 

[摘要]Dithiothreitol efficiently reduces carbohydrate azides in aqueous acetonitrile to give good-to-excellent yields of the corresponding amines or, after N-acetylation, acetamides. This reduction can proceed in either the presence or the absence of a base.

 
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