Multimetallic Schiff Base Complexes as Cooperative Asymmetric Catalysts

[摘要]：Multimetallic salen and related Schiff base complexes designed for cooperative asymmetric catalysis are introduced. First, studies to enhance the cooperative function of two distinct metal-salen units using covalently linked metal-salen complexes, supramolecular bimetallic salens as well as mu-oxo-bridged metal salens are described. Then, studies to design dinuclear Schiff base catalysts that exhibit unique intramolecular cooperative functions of two distinct metals are discussed in detail.

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