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Hydrophosphonylation of Benzoylhydrazones Using Iodine as a Catalyst: A Facile Synthesis of alpha-(N '-Acylhydrazino)-Substituted Phosphonates

  作者 DAS BISWANATH; KUMAR JAYPRAKASH NARAYAN; KUMAR AVULA SATYA; KANTH BODDU SHASHI  
  选自 期刊  Synthesis;  卷期  2010年-18;  页码  3113-3116  
  关联知识点  
 

[摘要]A simple and efficient method for the synthesis of alpha-(N'-acylhydrazino)-substituted phosphonates has been developed using the hydrophosphonylation of benzoylhydrazones with triethyl phosphite in the presence of iodine as a catalyst at room temperature. The products are formed in excellent yields (89-95%) within two to three hours.

 
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