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Enhancement of ferromagnetic properties in Zn0.95Co0.05O nanoparticles by indium codoping: An experimental and theoretical study

  作者 Jayakumar, OD; Sudakar, C; Persson, C; Salunke, HG; Naik, R; Tyagi, AK  
  选自 期刊  Applied Physics Letters;  卷期  2010年97-23;  页码  232510-232510  
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[摘要]Nanoparticles of Zn0.95-xCo0.05InxO (x = 0.0 to 0.07) were synthesized by the pyrolitic reaction of sol-gels obtained from respective metal precursors. X-ray diffraction and high-resolution transmission electron microscopy studies confirm the formation of impurity-free wurtzite type ZnO structure for all the compositions. While pristine ZnO is diamagnetic, Zn0.95Co0.05O nanoparticles show weak paramagnetic behavior at room temperature. When "In." is codoped with Co with x = 0.0 to 0.07 in Zn0.95-xCo0.05InxO, a systematic increase in magnetic moment is observed up to x = 0.07. First-principles modeling supports that the ferromagnetic phase become more favorable at higher indium doping concentrations. (C) 2010 American Institute of Physics. [doi:10.1063/1.3517450]

 
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