Catalytic Asymmetric Friedel-Crafts/Protonation of Nitroalkenes and N-Heteroaromatics

[摘要]：The catalytic asymmetric Friedel-Crafts/protonation of indoles and pyrroles with a-substituted nitroalkenes to give the corresponding adducts in a highly anti-selective manner was achieved by an imidazoline aminophenol (L2)-Cu complex. The anti-adducts could be successfully transformed to biochemically important alpha-substituted beta-heteroarylalkylamines.

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