Bronsted-acid-catalyzed activation of nitroalkanes: a direct enantioselective aza-Henry reaction.

[摘要]：A direct asym. organocatalytic aza-Henry reaction has been developed. A bifuctional Bronsted-acid-catalyzed activation of nitroalkanes provided an efficient access to a,b-diamino acids with high dia- and enantioselectivities under mild and base-free reaction conditions.

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