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Modified Julia-Kocienski Reaction Promoted by Means of m-NPT (Nitrophenyltetrazole) Sulfone

  作者 SAKAI YUKI; IKEUCHI KAZUTADA; YAMADA YUJI; WAKIMOTO TOSHIYUKI; KAN TOSHIYUKI  
  选自 期刊  SYNLETT;  卷期  2010年-5;  页码  827-829  
  关联知识点  
 

[摘要]m-Nitrophenyltetrazole sulfone (2) was employed in the Julia-Kocienski reaction. The olefination reaction between 2 and carbonyl compounds proceeded smoothly under Masamune-Roush conditions (DBU and LiCl). These conditions were also applicable to our catechin derivative synthesis. Furthermore, phenolic mesylate was also tolerated in this mild reaction.

 
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