Synthesis of Paracyclophane Thiols via an Unprecedented Reduction-Deprotection Sequence: Direct Conversion of tert-Butyl Sulfoxides into Thiols with Boron Tribromide

[摘要]：Starting from readily available paracyclophane-substituted sulfoxides, a two-step procedure including a directed orthometalation and an unprecedented deoxygenation-deprotection sequence allows the generation of versatile functionalized paracyclophane thiols.

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