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Regioselective synthesis of functionalized 3-(methylthio)phenols by the first formal [3+3] cyclocondensations of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with 1,1-bis(methylthio)-1-en-3-ones.

  作者 Lubbe, Mathias;Klassen, Renske;Trabhardt, Tiana;Villinger, Alexander;Langer, Peter;  
  选自 期刊  SYNLETT;  卷期  2008年-15;  页码  2331-2333  
  关联知识点  
 

[摘要]The [3+3] cyclocondensation of 1,3-bis(silyl enol ethers) with 1,1-bis(methylthio)-1-en-3-ones results in the regioselective formation of 3-(methylthio)phenols. The products represent useful synthetic building blocks, which are not readily available by other methods.

 
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