个性化文献订阅>期刊> Organic Letters
 

Highly Enantioselective and Efficient Organocatalytic Aldol Reaction of Acetone and beta,gamma-Unsaturated alpha-Keto Ester

  作者 LI PENGFEI; ZHAO JUNLING; LI FENGBO; CHAN ALBERT S C; KWONG FUK YEE  
  选自 期刊  Organic Letters;  卷期  2010年12-24;  页码  5616-5619  
  关联知识点  
 

[摘要]An effective organocatalytic asymmetric aldol reaction of acetone to beta,gamma-unsaturated alpha-keto ester has been developed. In the presence of 5 mol % of 9-amino (9-deoxy)-epicinchona alkaloid and 10 mol A of 4-nitrobenzoic acid, the aldol adducts containing a chiral tertiary alcohol moiety were obtained in excellent yields and enantioselectivities.

 
      被申请数(0)  
 

[全文传递流程]

一般上传文献全文的时限在1个工作日内