Chiral Ruthenium Lewis Acid Catalyzed Intramolecular Diels-Alder Reactions

[摘要]：Single point binding ruthenium Lewis acid catalysts [Ru(acetone)(S,S)-BIPHOP-F)CpliSbF(6)] ((S,S)-1b) and [Ru(acetone)(S,S)-BIPHOP-F)(indenyl)[SbF6] ((S,S)-1c) efficiently catalyze intramolecular Diels-Alder (IMDA) reactions under mild conditions to afford the endo cycloaddition products as the major product in excellent yields with high diastereo-and enantioselectivities.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内