Recent developments on hemilabile P,O-type ligands in cross-coupling reactions.

[摘要]：A review describes the concepts of and recent developments on monophosphine P,O-type ligands. The attractive synthetic pathways to these ligands are highlighted, and the applications of the ligands in cross-coupling reactions are fully illustrated. The hemilabile properties of P,O-type ligands on complexation with transition metals are also discussed.

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