A facile aerobic copper-catalyzed a-oxygenation of aryl thioacetamides: an efficient access to a-keto aryl thioamides.

[摘要]：Copper(II) efficiently catalyzes the aerobic oxidn. of aryl thioacetamides into the corresponding a-keto aryl thioamides in moderate to high yields in the presence of K2CO3 under O2 atmosphere. This protocol is simple, clean, and generates water as the only byproduct. A mechanism is proposed for the reaction course.

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