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A Properly Protected Sphingosine Acceptor for Helferich Glycosylation

  作者 MICHIELETTI MARIO; SILLANI LAURA; PANZA LUIGI  
  选自 期刊  SYNLETT;  卷期  2009年-16;  页码  2609-2612  
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[摘要]The synthesis and some examples of glycosylations of a properly protected sphingosine is presented. This compound is suitable for the preparation of glycosphingolipids. It has been used for the synthesis of alpha-mannosylceramide and sulfatide exploiting the anchimeric assistance to address the stereochemistry of the glycosidic bond.

 
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