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Ring-Conformer Effects of the Cyclopropyl Group: First Use of trans-(2R,3R)-Cyclopropanecarbaldehydes as Electrophiles in Diastereoselective Baylis-Hillman Reaction

  作者 KRISHNA PALAKODETY RADHA; KISHORE S; REDDY P SRINIVAS  
  选自 期刊  SYNLETT;  卷期  2009年-16;  页码  2605-2608  
  关联知识点  
 

[摘要]trans-(2R,3R)-Cyclopropanecarbaldehydes are used as novel electrophiles in the Baylis-Hillman reaction to afford adducts in good yields (75-85%) and diastereoselectivities (60-90%).

 
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