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Diastereoselective Tin-Free Tandem Radical Additions to 3-Formylchromones

  作者 ZIMMERMAN JAKE R; MANPADI MADHURI; SPATNEY RUSSELL; BAKER AARON  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-19;  页码  8076-8081  
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[摘要]A tin-free tandem radical addition methodology onto 3-formylchromones is presented. This radical process yields functionalized chromone structures via two carbon carbon bond-forming steps. These products contain up to three contiguous stereocenters with good to excellent dr's and yields.

 
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