Covalently Chemical Modification of Lithium Ion-Encapsulated Fullerene: Synthesis and Characterization of [Li+@PCBM]PF6-

[摘要]：Covalently organic derivatization of [Li+@C-60]PF6- to obtain Li+-encapsulated PCBM, [Li+@PCBM]PF6-, is described. Synthetic procedures, electrochemical properties, light absorption properties, details of isomerization from [5,6]- to [6,6]-isomer, and X-ray crystal structure of [Li+@PCBM]PF6- are discussed.

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