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Halogenation of Primary Alcohols Using a Tetraethylammonium Halide/[Et2NSF2]BF4 Combination

  作者 POULIOT MARIEFRANCE; MAHE OLIVIER; HAMEL JEANDENYS; DESROCHES JUSTINE; PAQUIN JEANFRANCOIS  
  选自 期刊  Organic Letters;  卷期  2012年14-21;  页码  5428-5431  
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[摘要]The halogenation of primary alcohols is presented. The use of a combination of tetraethylammonium halide and [Et2NSF2]BF4 (XtalFluor-E) allows for chlorination and bromination reactions to proceed efficiently (up to 92% yield) with a wide range of alcohols. Iodination reactions are also possible albeit in lower yields.

 
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